Shame I gotta......KILL THE DOG!!!

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No, I'm just yankin your chain. I do need a little advice though. This little Chihuahua pictured here is Tiffy, we also have four Boston Terriers, all are indoor, outdoor dogs. For the most part, relieving themselves in the house isn't an issue. The bigger dogs will go outside, with the exception of if it's storming and they can't hold it, it which case we might find a surprise when we get up in the morning. The chihuahua uses her puppy pads faithfully, she also uses the doormats by the front door, the front porch, right at the bottom of the step because she's too lazy to walk a few feet on either side of the step. The strange thing is, she knows what she's doing in the house because she never does it when one of us can actually catch her at it. We have new flooring put down, no more carpet for me. I need something by the front door for us to wipe our feet on, I don't want dog pee to be on it. Is there a natural repellent we can spray the doormat with that won't cost an arm and a leg. I told my husband I thought I was going to put some moth balls in a bottle of water and spray around outside where I don't want her to go. I would rather smell the lingering scent of moth balls (gag) then dog pee that has been warmed by the hot, humid days we have here.