night shots.

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I haven't done much of any photography, but I happened to have my old manual camera with me on my way back from work. There is a beautiful spot on PA route 100, just where it diverges from route 29 N, where you can see all of allentown lit up. I took a whole bunch of shots, with various shutter speeds and aperture settings, but I was wondering what combinations are really the most effective for getting a.) clear, well defined shots, and b.) cool/eerie lighting effects? Once I get the pics back from the lab, I'll post them up.